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Methyl magnesium bromide 3M solution in ethyl ether

CAT: 0286-M21530Size: 100 mLDry Ice: NoHazardous: Yes
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CAT#:0286-M21530Size:100 mL
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CAS Number
75-16-1
Synonyms
Bromomethylmagnesium
UN Code
UN1928
Pictogram
02 - Flammable; 05 - Corrosive; 07 - Irritant
UDF Signal Word
Danger
MDL Number
MFCD00000041
Hazard Statement
H225 Highly flammable liquid and vapor; H260 In contact with water releases flammable gases which may ignite spontaneously; H302 Harmful if swallowed; H312 Harmful in contact with skin; H314 Causes severe skin burns and eye damage; H318 Causes serious eye damage; H332 Harmful if inhaled; H335 May cause respiratory irritation; H336 May cause drowsiness or dizziness.
Other Statements
EUH014 Reacts violently with water; EUH019 May form explosive peroxides
DOT Name
Methyl Magnesium Bromide in Ethyl Ether
DOT Classification
Class 4.3, 3
Packaging Group
PGI
Precautions
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking; P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire; P231+P232 Handle under inert gas. Protect from moisture; P240 Ground/bond container and receiving equipment; P250 Do not subject to grinding/shock/[ ]/friction; P260 Do not breathe dust/fume/gas/mist/vapors/spray; P280 Wear protective gloves/protective clothing/eye protection/face protection; P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting; P302+P352 IF ON SKIN: wash with plenty of soap and water; P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing; P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing; P332+P313 IF SKIN irritation occurs: Get medical advice/attention.

Chemical Information

Methyl magnesium bromide

Methyl magnesium bromide in ethyl ether appears as a colorless cloudy solution in diethyl ether. Vapors heavier than air.

CAS Number75-16-1
PubChem CID6349
IUPAC Namemagnesium;carbanide;bromide
Molecular FormulaCH3BrMg
Molecular Weight119.24
Topological Polar Surface Area0
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count2
Rotatable Bond Count0
Heavy Atom Count3
Formal Charge0
Complexity4
SMILES
[CH3-].[Mg+2].[Br-]
InChI
InChI=1S/CH3.BrH.Mg/h1H3;1H;/q-1;;+2/p-1
InChIKey
NXPHGHWWQRMDIA-UHFFFAOYSA-M
Chemical Structure
2D Structure
2D structure of Methyl magnesium bromide
CAS: 75-16-1
CID: 6349
Formula: CH3BrMg
MW: 119.24
Interactive 3D Structure
Loading 3D structure...
View on PubChemRaw 3D data
Computed Properties
PropertyValue
Molecular Weight119.24
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count2
Rotatable Bond Count0
Exact Mass117.92685
Monoisotopic Mass117.92685
Topological Polar Surface Area0 Ų
Heavy Atom Count3
Formal Charge0
Complexity4.8
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
Covalently-Bonded Unit Count3
Compound Is CanonicalizedYes

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